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Ruthenium porphyrin catalysed intermolecular amino-oxyarylation of alkenes to give primary amines via a ruthenium nitrido intermediate

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Abstract

Ruthenium porphyrin catalysed direct intermolecular amino-oxyarylation of alkenes including styrenes and 1,3-dienes to give primary amines with O-(2,4-dinitrophenyl)hydroxylamine as the amine source was achieved in moderate to good yields under mild reaction conditions. Spectroscopic analyses revealed that a ruthenium nitrido complex was the key reaction intermediate for the amino-oxyarylation reaction.

Graphical abstract: Ruthenium porphyrin catalysed intermolecular amino-oxyarylation of alkenes to give primary amines via a ruthenium nitrido intermediate

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Publication details

The article was received on 15 Oct 2019, accepted on 21 Nov 2019 and first published on 22 Nov 2019


Article type: Communication
DOI: 10.1039/C9CC08043K
Chem. Commun., 2020, Advance Article

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    Ruthenium porphyrin catalysed intermolecular amino-oxyarylation of alkenes to give primary amines via a ruthenium nitrido intermediate

    D. Yu, K. Shing, Y. Liu, H. Liu and C. Che, Chem. Commun., 2020, Advance Article , DOI: 10.1039/C9CC08043K

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