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Chemical evidence of the stability of praseodymium(v) in gas-phase oxide nitrate complexes

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Abstract

The diverse reactivity of [LnO2(NO3)2] complexes with water in the gas phase, for Ln = Ce, Pr and Nd, examined in a quadrupole ion trap and complemented by ab initio computations, illuminates the chemical stability of Pr in the unusual +5 oxidation state.

Graphical abstract: Chemical evidence of the stability of praseodymium(v) in gas-phase oxide nitrate complexes

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Publication details

The article was received on 12 Oct 2019, accepted on 01 Nov 2019 and first published on 01 Nov 2019


Article type: Communication
DOI: 10.1039/C9CC08006F
Chem. Commun., 2019, Advance Article

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    Chemical evidence of the stability of praseodymium(V) in gas-phase oxide nitrate complexes

    B. Monteiro, N. A. G. Bandeira, C. Lourenço, A. F. Lucena, J. M. Carretas, J. K. Gibson and J. Marçalo, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC08006F

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