Issue 90, 2019
From the journal:

Chemical Communications

Biomimetic synthesis of nudicaulins I and II, yellow pigments from the Iceland poppy Papaver nudicaule†

Rory Devlina  and  Jonathan Sperry ORCID logo *a  

* Corresponding authors

a School of Chemical Sciences, University of Auckland, 23 Symonds Street, Auckland, New Zealand
E-mail: j.sperry@auckland.ac.nz

Abstract

Indole and the anthocyanin orientalin proceed through a unique cascade sequence that leads to nudicaulins I and II in 92% yield. This biomimetic synthesis confirms the biosynthesis proposal for these structurally unprecedented flavoalkaloids that play a key role in the colour range displayed by the Iceland poppy.

Graphical abstract: Biomimetic synthesis of nudicaulins I and II, yellow pigments from the Iceland poppy Papaver nudicaule

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Article information

DOI
https://doi.org/10.1039/C9CC07943B
Article type
Communication
Submitted
10 Oct 2019
Accepted
18 Oct 2019
First published
21 Oct 2019

Chem. Commun., 2019,55, 13594-13597

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Biomimetic synthesis of nudicaulins I and II, yellow pigments from the Iceland poppy Papaver nudicaule

R. Devlin and J. Sperry, Chem. Commun., 2019, 55, 13594 DOI: 10.1039/C9CC07943B

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