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Mechanism of C–P bond formation via Pd-catalyzed decarbonylative phosphorylation of amides: insight into the chemistry of the second coordination sphere

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Abstract

We report on the basis of DFT computations a plausible and detailed reaction mechanism for the first Pd-catalyzed decarbonylative phosphorylation of amides forming C–P bonds, which reveals, among other things, crucial events in the second coordination sphere, including ion pair and hydrogen bonding interactions as well as proton transfer.

Graphical abstract: Mechanism of C–P bond formation via Pd-catalyzed decarbonylative phosphorylation of amides: insight into the chemistry of the second coordination sphere

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The article was received on 09 Oct 2019, accepted on 23 Nov 2019 and first published on 25 Nov 2019


Article type: Communication
DOI: 10.1039/C9CC07923H
Chem. Commun., 2020, Advance Article

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    Mechanism of C–P bond formation via Pd-catalyzed decarbonylative phosphorylation of amides: insight into the chemistry of the second coordination sphere

    W. Tong, T. D. Ly, T. Zhao, Y. Wu and X. Wang, Chem. Commun., 2020, Advance Article , DOI: 10.1039/C9CC07923H

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