A palladium–carbon-connected organometallic framework and its catalytic application

Abstract

Herein, we report an organometallic framework (OMF) generated from a divergent tridentate arylisocyanide ligand and PdI₂ under solvothermal conditions. The obtained Pd–C bond-connected two-dimensional Pd-OMF was crystalline and porous. Moreover, it could be a highly active catalyst to promote the Suzuki–Miyaura cross-coupling reaction in a heterogeneous manner.