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Hydrophilicity and Oxophilicity of Isolated CaMn4O5 Cationic Cluster Modeling Inorganic Core of Oxygen-Evolving Complex

Abstract

The bond splitting and oxidation of water, is known to be catalyzed in photosystem II, which consists of protein ligands and an inorganic core, CaMn4O5. In the present study, redox properties of isolated CaMn4Ok+ clusters and the effect of water on them were investigated by gas phase thermal desorption spectrometry and density functional theory (DFT) calculations.

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Publication details

The article was received on 05 Oct 2019, accepted on 05 Nov 2019 and first published on 05 Nov 2019


Article type: Communication
DOI: 10.1039/C9CC07818E
Chem. Commun., 2019, Accepted Manuscript

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    Hydrophilicity and Oxophilicity of Isolated CaMn4O5 Cationic Cluster Modeling Inorganic Core of Oxygen-Evolving Complex

    Y. Zhang, D. Masuzaki and F. Mafune, Chem. Commun., 2019, Accepted Manuscript , DOI: 10.1039/C9CC07818E

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