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Synthesis of pyridyl carbyne complexes and their conversion to N-heterocyclic vinylidenes

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Abstract

A new synthetic approach to hetero-aryl substituted carbyne complexes has allowed the synthesis of pyridyl functionalised carbynes and bis(carbynes), alkylation of which affords the first N-heterocyclic vinylidene complexes.

Graphical abstract: Synthesis of pyridyl carbyne complexes and their conversion to N-heterocyclic vinylidenes

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Publication details

The article was received on 03 Oct 2019, accepted on 25 Nov 2019 and first published on 25 Nov 2019


Article type: Communication
DOI: 10.1039/C9CC07760J
Chem. Commun., 2019, Advance Article

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    Synthesis of pyridyl carbyne complexes and their conversion to N-heterocyclic vinylidenes

    B. J. Frogley and A. F. Hill, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC07760J

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