Synthesis of pyridyl carbyne complexes and their conversion to N-heterocyclic vinylidenes†
Benjamin J.
Frogley 
a
and
Anthony F.
Hill
*a
a
and
Anthony F.
Hill
*a
Abstract
A new synthetic approach to hetero-aryl substituted carbyne complexes has allowed the synthesis of pyridyl functionalised carbynes and bis(carbynes), alkylation of which affords the first N-heterocyclic vinylidene complexes.
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