Jump to main content
Jump to site search


Bridging selenocarbonyl ligands: an open and shut case

Author affiliations

Abstract

Novel bis(isoselenocarbonyl) complexes [W2Pt(μ-CSe)2(CO)4(L2)(Tp*)2] (L2 = cyclooctadiene, norbornadiene) eliminate the diene upon heating to provide [W2Pt(μ-CSe)2(CO)4(Tp*)2], in which the CSe ligands close to bridge W–Pt bonds in a σ–π mode that may be re-opened by addition of new ligands (CNR: R = tBu, C6H2Me3) to re-establish the isoselenocarbonyl coordination in [W2Pt(μ-CSe)2(CO)4(CNR)2(Tp*)2].

Graphical abstract: Bridging selenocarbonyl ligands: an open and shut case

Back to tab navigation

Supplementary files

Publication details

The article was received on 02 Oct 2019, accepted on 28 Oct 2019 and first published on 28 Oct 2019


Article type: Communication
DOI: 10.1039/C9CC07757J
Chem. Commun., 2019, Advance Article

  •   Request permissions

    Bridging selenocarbonyl ligands: an open and shut case

    B. J. Frogley, A. F. Hill and L. J. Watson, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC07757J

Search articles by author

Spotlight

Advertisements