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Anion ligand promoted selective C–F bond reductive elimination enables C(sp2)–H fluorination

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Abstract

A detailed mechanism study on the anion ligand promoted selective C–H bond fluorination is reported. The role of the anion ligand has been clarified by experimental evidence and DFT calculations. Moreover, the nitrate promoted C–F bond reductive elimination enabled a selective C–H bond fluorination of various symmetric and asymmetric azobenzenes to access diverse o-fluoroanilines.

Graphical abstract: Anion ligand promoted selective C–F bond reductive elimination enables C(sp2)–H fluorination

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Publication details

The article was received on 02 Oct 2019, accepted on 04 Nov 2019 and first published on 05 Nov 2019


Article type: Communication
DOI: 10.1039/C9CC07726J
Chem. Commun., 2019, Advance Article

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    Anion ligand promoted selective C–F bond reductive elimination enables C(sp2)–H fluorination

    Y. Mao, G. Luo, H. Hao, Z. Xu, S. Lou and D. Xu, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC07726J

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