Jump to main content
Jump to site search


Generation of a zinc and rhodium containing metallomacrocycle by rearrangement of a six-coordinate precursor complex

Abstract

Two pentadentate N3,P2 ligands coordinate zinc(II) by their N3 pocket. Four free phosphine donors allow the coordination of four AuCl moieties leading to a pentanuclear ZnAu4 complex. In con-trast, the attempt to use the phosphines for chelating coordination of two Rh(CO)Cl units results in a well-organized rearrangement that ends up with the formation of a metallomacrocycle in high yields.

Back to tab navigation

Supplementary files

Publication details

The article was received on 01 Oct 2019, accepted on 25 Nov 2019 and first published on 26 Nov 2019


Article type: Communication
DOI: 10.1039/C9CC07723E
Chem. Commun., 2019, Accepted Manuscript

  •   Request permissions

    Generation of a zinc and rhodium containing metallomacrocycle by rearrangement of a six-coordinate precursor complex

    C. Groß, Y. Sun, T. Jost, T. Grimm, M. P. Klein, G. Niedner-Schatteburg, S. Becker and W. R. Thiel, Chem. Commun., 2019, Accepted Manuscript , DOI: 10.1039/C9CC07723E

Search articles by author

Spotlight

Advertisements