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Generation of a zinc and rhodium containing metallomacrocycle by rearrangement of a six-coordinate precursor complex

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Abstract

Two pentadentate N3,P2 ligands coordinate zinc(II) by their N3 pocket. Four free phosphine donors allow the coordination of four AuCl moieties leading to a pentanuclear ZnAu4 complex. In contrast, the attempt to use the phosphines for chelating coordination of two Rh(CO)Cl units results in a well-organized rearrangement that ends up with the formation of a metallomacrocycle in high yields.

Graphical abstract: Generation of a zinc and rhodium containing metallomacrocycle by rearrangement of a six-coordinate precursor complex

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Publication details

The article was received on 01 Oct 2019, accepted on 25 Nov 2019 and first published on 26 Nov 2019


Article type: Communication
DOI: 10.1039/C9CC07723E
Chem. Commun., 2020, Advance Article

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    Generation of a zinc and rhodium containing metallomacrocycle by rearrangement of a six-coordinate precursor complex

    C. Groß, Y. Sun, T. Jost, T. Grimm, M. P. Klein, G. Niedner-Schatteburg, S. Becker and W. R. Thiel, Chem. Commun., 2020, Advance Article , DOI: 10.1039/C9CC07723E

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