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Issue 91, 2019
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Preparation and crystal structures of the beryllium ammines [Be(NH3)4]X2 (X = Br, I, CN, SCN, N3) and Be(NH3)2X'2 (X' = Cl, Br, I)

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Abstract

Tetraammineberyllium halides and pseudo-halides [Be(NH3)4]X2 (X = Cl, Br, I, CN, SCN, N3) as well as Be(NH3)2F2 have been prepared from beryllium metal and NH4X or NH4F in liquid ammonia at ambient temperature, respectively. Diammineberyllium halides Be(NH3)2X'2 (X' = Cl, Br, I) were synthesized at 300 °C from Be and NH4X'. The obtained compounds were characterised via X-ray diffraction, and IR and Raman spectroscopy and their thermal decomposition was studied by TGA.

Graphical abstract: Preparation and crystal structures of the beryllium ammines [Be(NH3)4]X2 (X = Br, I, CN, SCN, N3) and Be(NH3)2X'2 (X' = Cl, Br, I)

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Publication details

The article was received on 01 Oct 2019, accepted on 15 Oct 2019 and first published on 15 Oct 2019


Article type: Communication
DOI: 10.1039/C9CC07712J
Chem. Commun., 2019,55, 13649-13652

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    Preparation and crystal structures of the beryllium ammines [Be(NH3)4]X2 (X = Br, I, CN, SCN, N3) and Be(NH3)2X'2 (X' = Cl, Br, I)

    M. Müller and M. R. Buchner, Chem. Commun., 2019, 55, 13649
    DOI: 10.1039/C9CC07712J

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