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Versatile, one-pot introduction of nonahalogenated 2-ammonio-decaborate ions as boron cluster scaffolds into organic molecules; host–guest complexation with γ-cyclodextrin

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Abstract

We report the modification of the 2-ammonio group at halogenated decaborate ions with 2,3-epoxypropane, the product of which reacts readily with nucleophiles to form previously inaccessible coupling of polyhedra with organic molecules and materials. We demonstrate that these ions present a good binding motif in supramolecular chemistry.

Graphical abstract: Versatile, one-pot introduction of nonahalogenated 2-ammonio-decaborate ions as boron cluster scaffolds into organic molecules; host–guest complexation with γ-cyclodextrin

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Publication details

The article was received on 30 Sep 2019, accepted on 21 Oct 2019 and first published on 21 Oct 2019


Article type: Communication
DOI: 10.1039/C9CC07678F
Chem. Commun., 2019, Advance Article

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    Versatile, one-pot introduction of nonahalogenated 2-ammonio-decaborate ions as boron cluster scaffolds into organic molecules; host–guest complexation with γ-cyclodextrin

    S. El Anwar, K. I. Assaf, B. Begaj, M. A. Samsonov, Z. Růžičková, J. Holub, D. Bavol, W. M. Nau, D. Gabel and B. Grűner, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC07678F

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