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Nickel-catalyzed exo-selective hydroacylation/Suzuki cross-coupling reaction

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Abstract

The first nickel-catalyzed intramolecular hydroacylation/Suzuki cross coupling cascade of o-allylbenzaldehydes with a broad range of phenylboronic acid neopentyl glycol esters has been developed. This strategy shows high regioselectivity and step economy in the construction of two C–C bonds via aldehyde C–H bond activation, affording valuable indanones with high efficiency.

Graphical abstract: Nickel-catalyzed exo-selective hydroacylation/Suzuki cross-coupling reaction

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Publication details

The article was received on 26 Sep 2019, accepted on 15 Nov 2019 and first published on 18 Nov 2019


Article type: Communication
DOI: 10.1039/C9CC07558E
Chem. Commun., 2019, Advance Article

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    Nickel-catalyzed exo-selective hydroacylation/Suzuki cross-coupling reaction

    S. Lee, L. Guo and M. Rueping, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC07558E

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