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Synthesis of structured polysiloxazanes via a Piers–Rubinsztajn reaction

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Abstract

A series of siloxazanes were successfully prepared by a Piers–Rubinsztajn reaction between methoxydisilazanes and the corresponding hydrosilanes. Polysiloxazanes with narrow dispersion were also synthesized from methoxydisilazanes and Si–H terminated oligosiloxanes. The possible interaction mechanism between tris(pentafluorophenyl)borane and the methoxydisilazane was investigated.

Graphical abstract: Synthesis of structured polysiloxazanes via a Piers–Rubinsztajn reaction

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Publication details

The article was received on 18 Sep 2019, accepted on 24 Oct 2019 and first published on 24 Oct 2019


Article type: Communication
DOI: 10.1039/C9CC07312D
Chem. Commun., 2019, Advance Article

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    Synthesis of structured polysiloxazanes via a Piers–Rubinsztajn reaction

    L. Ai, Y. Chen, L. He, Y. Luo, S. Li and C. Xu, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC07312D

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