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Calcium stannyl formation by organostannane dehydrogenation

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Abstract

Reaction of the dimeric calcium hydride, [(BDI)CaH]2 (1), with Ph3SnH ensues with elimination of H2 to provide [(BDI)Ca-μ2-H-(SnPh3)Ca(BDI)] (3) and [(BDI)Ca(SnPh3)]2 (4) alongside dismutation to Ph4Sn, H2 and Sn(0). DFT analysis indicates that stannyl anion formation occurs through deprotonation of Ph3SnH and with retention of dinuclear species throughout the reactions.

Graphical abstract: Calcium stannyl formation by organostannane dehydrogenation

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Publication details

The article was received on 17 Sep 2019, accepted on 02 Oct 2019 and first published on 03 Oct 2019


Article type: Communication
DOI: 10.1039/C9CC07289F
Chem. Commun., 2019, Advance Article
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    Calcium stannyl formation by organostannane dehydrogenation

    L. J. Morris, M. S. Hill, I. Manners, C. L. McMullin, M. F. Mahon and N. A. Rajabi, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC07289F

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