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An EDA Complex Directed N-centred Radical Generation from Nitrosoarene: A Divergent Synthetic Approach

Abstract

A metal-free strategy for the generation of N-centred radical from nitrosoarene (activated by allylsulfone) via an EDA complex directed single electron transfer (SET) process by diisopropylethylamine (iPr2NEt) or Hantzsch ester (HE) is reported. These mild and operationally simple protocol is initiated by the formation of C–N bond can either conclude to isoxazolidine or aziridine derivatives or can be transformed to β-amino acid derivatives.

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Publication details

The article was received on 18 Sep 2019, accepted on 11 Oct 2019 and first published on 11 Oct 2019


Article type: Communication
DOI: 10.1039/C9CC07277B
Chem. Commun., 2019, Accepted Manuscript

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    An EDA Complex Directed N-centred Radical Generation from Nitrosoarene: A Divergent Synthetic Approach

    I. Chatterjee, S. Ghosh, G. Kumar, N. Naveen and S. Pradhan, Chem. Commun., 2019, Accepted Manuscript , DOI: 10.1039/C9CC07277B

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