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Mass spectrometric detection of enantioselectivity in three-component complexation, copper(ii)-chiral tetradentate ligand-free amino acid in solution

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Abstract

By using electrospray ionization mass spectrometry coupled with the use of deuterium-labelled quasienantiomers, enantioselective coordination of a free amino acid as the second ligand of a copper(II) complex with a novel chiral tetradentate ligand was evaluated quantitatively in a short measurement time.

Graphical abstract: Mass spectrometric detection of enantioselectivity in three-component complexation, copper(ii)-chiral tetradentate ligand-free amino acid in solution

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Publication details

The article was received on 15 Sep 2019, accepted on 01 Nov 2019 and first published on 11 Nov 2019


Article type: Communication
DOI: 10.1039/C9CC07231D
Chem. Commun., 2020, Advance Article

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    Mass spectrometric detection of enantioselectivity in three-component complexation, copper(II)-chiral tetradentate ligand-free amino acid in solution

    T. Nakakoji, H. Sato, D. Ono, H. Miyake, S. Shinoda, H. Tsukube, H. Kawasaki, R. Arakawa and M. Shizuma, Chem. Commun., 2020, Advance Article , DOI: 10.1039/C9CC07231D

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