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Acid-catalyzed synthesis of condensed polycyclic diaryl ethers from arenols

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Abstract

Diaryl ethers containing condensed polycyclic aryl groups were synthesized from arenols in the presence of a catalytic amount of p-chlorobenzenesulfonic acid. Symmetrical binaphthyl, biphenanthryl, and bipyrenyl ethers were obtained in high yields. Unsymmetrical derivatives were also synthesized from 9-phenanthrol and arenols, using combinations of reactive and unreactive substrates.

Graphical abstract: Acid-catalyzed synthesis of condensed polycyclic diaryl ethers from arenols

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Publication details

The article was received on 13 Sep 2019, accepted on 31 Oct 2019 and first published on 01 Nov 2019


Article type: Communication
DOI: 10.1039/C9CC07172E
Chem. Commun., 2019, Advance Article

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    Acid-catalyzed synthesis of condensed polycyclic diaryl ethers from arenols

    S. Tanii, M. Arisawa and M. Yamaguchi, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC07172E

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