A single-crystal-to-single-crystal transformation affording photochromic 3D MORF crystals

Xue Yang; Michel Giorgi; Hakim Karoui; Didier Gigmes; Virginie Hornebecq; Olivier Ouari; Anthony Kermagoret; David Bardelang

doi:10.1039/C9CC07121K

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A single-crystal-to-single-crystal transformation affording photochromic 3D MORF crystals†

Xue Yang,^a Michel Giorgi,

^b Hakim Karoui,^a Didier Gigmes,^a Virginie Hornebecq,^c Olivier Ouari,

^a Anthony Kermagoret

*^a and David Bardelang

*^a

Author affiliations

* Corresponding authors

^a Aix Marseille Univ, CNRS, ICR, Marseille, France
E-mail: anthony.kermagoret@univ-amu.fr, david.bardelang@univ-amu.fr

^b Aix Marseille Univ, CNRS, Centrale Marseille, FSCM, Marseille, France

^c Aix Marseille Univ, CNRS, MADIREL, Marseille, France

Abstract

Metal–organic framework (MOF) type crystals in which rigid, viologen-based pillars are surrounded by cucurbit[7]uril (CB[7]) macrocycles are described. These metal–organic rotaxane frameworks (MORF) are obtained by desolvation of a crystal precursor featuring a network already near-optimal toward 3D metal–ligand reticulation and show reversible photochromism.

This article is part of the themed collection: Cucurbiturils and related cavitands

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Article information

DOI: https://doi.org/10.1039/C9CC07121K
Article type: Communication
Submitted: 11 Sep 2019
Accepted: 22 Oct 2019
First published: 23 Oct 2019

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Chem. Commun., 2019,55, 13824-13827

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A single-crystal-to-single-crystal transformation affording photochromic 3D MORF crystals

X. Yang, M. Giorgi, H. Karoui, D. Gigmes, V. Hornebecq, O. Ouari, A. Kermagoret and D. Bardelang, Chem. Commun., 2019, 55, 13824 DOI: 10.1039/C9CC07121K

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Chemical Communications

A single-crystal-to-single-crystal transformation affording photochromic 3D MORF crystals†

Abstract

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A single-crystal-to-single-crystal transformation affording photochromic 3D MORF crystals

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