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Non-stoichiometric hydrated magnesium-doped calcium carbonate precipitation in ethanol

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Abstract

The effect of Mg2+ on the precipitation pathway of CaCO3 in absolute ethanol has been studied to investigate the role of ion solvation in the crystallization process. Our data reveal that high concentrations of Mg2+ promote the precipitation of an amorphous transient phase together with non-stoichometric hydrated phases of calcium carbonate.

Graphical abstract: Non-stoichiometric hydrated magnesium-doped calcium carbonate precipitation in ethanol

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Publication details

The article was received on 10 Sep 2019, accepted on 03 Oct 2019 and first published on 03 Oct 2019


Article type: Communication
DOI: 10.1039/C9CC07087G
Chem. Commun., 2019, Advance Article

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    Non-stoichiometric hydrated magnesium-doped calcium carbonate precipitation in ethanol

    G. Magnabosco, A. M. M. Condorelli, R. Rosenberg, I. Polishchuk, B. Pokroy, D. Gebauer, H. Cölfen and G. Falini, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC07087G

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