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Issue 83, 2019
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A rose bengal-functionalized porous organic polymer for carboxylative cyclization of propargyl alcohols with CO2

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Abstract

A Rose bengal-functionalized porous organic polymer (RB-POP) was prepared with a specific surface area of up to 562 m2 g−1. In the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene, RB-POP supported Ag(0) nanoparticles exhibited excellent performance for catalyzing cyclization of propargyl alcohols with CO2 at 30 °C, achieving a TOF of 5000 h−1, the highest value among the reported ones.

Graphical abstract: A rose bengal-functionalized porous organic polymer for carboxylative cyclization of propargyl alcohols with CO2

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Publication details

The article was received on 09 Sep 2019, accepted on 23 Sep 2019 and first published on 23 Sep 2019


Article type: Communication
DOI: 10.1039/C9CC07043E
Chem. Commun., 2019,55, 12475-12478

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    A rose bengal-functionalized porous organic polymer for carboxylative cyclization of propargyl alcohols with CO2

    X. Yu, Z. Yang, F. Zhang, Z. Liu, P. Yang, H. Zhang, B. Yu, Y. Zhao and Z. Liu, Chem. Commun., 2019, 55, 12475
    DOI: 10.1039/C9CC07043E

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