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Enantioselective palladium-catalyzed diarylation of unactivated alkenes

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Abstract

Enantioselective Pd-catalyzed diarylation of unactivated alkenes between arenediazonium salts and arylboronic acids has been developed. This method provides an efficient route to dihydrobenzofurans with all-carbon quaternary centers in good yields with 88–99% ee. This reaction proceeding under mild and open-flask conditions is compatible with a variety of functional groups, including cyano, ketone, ester, amide, bromine and free hydroxyl groups.

Graphical abstract: Enantioselective palladium-catalyzed diarylation of unactivated alkenes

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Publication details

The article was received on 09 Sep 2019, accepted on 01 Nov 2019 and first published on 01 Nov 2019


Article type: Communication
DOI: 10.1039/C9CC07036B
Chem. Commun., 2019, Advance Article

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    Enantioselective palladium-catalyzed diarylation of unactivated alkenes

    B. Ju, S. Chen and W. Kong, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC07036B

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