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The synthesis of bottlebrush cellulose-graft-diblock copolymer elastomers via atom transfer radical polymerization utilizing a halide exchange technique

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Abstract

A novel kind of bottlebrush cellulose-graft-diblock copolymer thermoplastic elastomer (Cell-g-PBA-b-PMMA) was synthesized by grafting from cellulose backbones via surface-initiated atom transfer radical polymerization (ATRP). The mechanical properties of the bottlebrush copolymer elastomers can be adjusted by controlling the block lengths and composition of the side chains.

Graphical abstract: The synthesis of bottlebrush cellulose-graft-diblock copolymer elastomers via atom transfer radical polymerization utilizing a halide exchange technique

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Publication details

The article was received on 10 Sep 2019, accepted on 26 Oct 2019 and first published on 04 Nov 2019


Article type: Communication
DOI: 10.1039/C9CC06982H
Chem. Commun., 2019, Advance Article

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    The synthesis of bottlebrush cellulose-graft-diblock copolymer elastomers via atom transfer radical polymerization utilizing a halide exchange technique

    J. Zhang, Z. Wang, X. Wang and Z. Wang, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC06982H

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