Jump to main content
Jump to site search


Magnetism in Ln molecular systems with 4f/valence-shell interplay (FV-magnetism)

Author affiliations

Abstract

The hunt for high-performance single-molecule magnets (SMM) revealed that atomic and molecular lanthanide systems combining 4f-shell and valence magnetism (FV-magnetism) may show magnetic bistability up to unexpectedly high temperatures. Here we rationalize the stability of the magnetism in the FV-systems from first principles on the example of LnII(CpiPr5)2 molecules.

Graphical abstract: Magnetism in Ln molecular systems with 4f/valence-shell interplay (FV-magnetism)

Back to tab navigation

Supplementary files

Publication details

The article was received on 04 Sep 2019, accepted on 28 Oct 2019 and first published on 28 Oct 2019


Article type: Communication
DOI: 10.1039/C9CC06913E
Chem. Commun., 2019, Advance Article

  •   Request permissions

    Magnetism in Ln molecular systems with 4f/valence-shell interplay (FV-magnetism)

    V. Dubrovin, A. A. Popov and S. Avdoshenko, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC06913E

Search articles by author

Spotlight

Advertisements