SCHEDULED MAINTENANCE
A homogeneous, redox-neutral photo fragmentation of diol derivatives was developed. Under photo/hydrogen atom transfer (HAT) dual catalysis, diol derivatives such as lignin model compounds and diol monoesters undergo selective β C(sp3)–O bond cleavage to afford ketones, phenols and acids effectively.
K. Chen, J. Schwarz, T. A. Karl, A. Chatterjee and B. König, Chem. Commun., 2019, 55, 13144 DOI: 10.1039/C9CC06904F
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