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Issue 99, 2019
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Catalytic reduction of dinitrogen to tris(trimethylsilyl)amine using rhodium complexes with a pyrrole-based PNP-type pincer ligand

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Abstract

Rhodium complexes bearing an anionic pyrrole-based PNP-type pincer ligand are synthesised and found to work as effective catalysts for the transformation of molecular dinitrogen into tris(trimethylsilyl)amine under mild reaction conditions. This is the first successful example of rhodium-catalysed dinitrogen reduction under mild reaction conditions.

Graphical abstract: Catalytic reduction of dinitrogen to tris(trimethylsilyl)amine using rhodium complexes with a pyrrole-based PNP-type pincer ligand

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Article information


Submitted
04 Sep 2019
Accepted
01 Nov 2019
First published
01 Nov 2019

Chem. Commun., 2019,55, 14886-14889
Article type
Communication

Catalytic reduction of dinitrogen to tris(trimethylsilyl)amine using rhodium complexes with a pyrrole-based PNP-type pincer ligand

R. Kawakami, S. Kuriyama, H. Tanaka, K. Arashiba, A. Konomi, K. Nakajima, K. Yoshizawa and Y. Nishibayashi, Chem. Commun., 2019, 55, 14886
DOI: 10.1039/C9CC06896A

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