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Highly Stereoselective Intramolecular Buchner Reaction of Diazoacetamides Catalyzed by a Ru(II)-Pheox Complex

Abstract

This work reports the first efficient enantioselective intramolecular Buchner reaction of diazoacetmides.The Ru-Pheox catalyst was shown to be highly efficient in this transformation in terms of both the regio- and enantioselectivity (up to 99% ee) giving the desired products in quantitative yield.

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Publication details

The article was received on 04 Sep 2019, accepted on 09 Oct 2019 and first published on 10 Oct 2019


Article type: Communication
DOI: 10.1039/C9CC06889A
Chem. Commun., 2019, Accepted Manuscript

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    Highly Stereoselective Intramolecular Buchner Reaction of Diazoacetamides Catalyzed by a Ru(II)-Pheox Complex

    N. Phan Thi Thanh , M. Tone, H. Inoue, I. Fujisawa and S. Iwasa, Chem. Commun., 2019, Accepted Manuscript , DOI: 10.1039/C9CC06889A

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