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Highly stereoselective intramolecular Buchner reaction of diazoacetamides catalyzed by a Ru(ii)–Pheox complex

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Abstract

This work reports the first efficient enantioselective intramolecular Buchner reaction of diazoacetamides. The Ru(II)–Pheox catalyst was shown to be highly efficient in this transformation in terms of both the regio- and enantioselectivity (up to 99% ee) giving the desired products in quantitative yield.

Graphical abstract: Highly stereoselective intramolecular Buchner reaction of diazoacetamides catalyzed by a Ru(ii)–Pheox complex

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Publication details

The article was received on 04 Sep 2019, accepted on 09 Oct 2019 and first published on 10 Oct 2019


Article type: Communication
DOI: 10.1039/C9CC06889A
Chem. Commun., 2019, Advance Article

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    Highly stereoselective intramolecular Buchner reaction of diazoacetamides catalyzed by a Ru(II)–Pheox complex

    N. Phan Thi Thanh, M. Tone, H. Inoue, I. Fujisawa and S. Iwasa, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC06889A

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