Cucurbit[7]uril promoted Fenton oxidation by modulating the redox property of catalysts

Bohan Tang; Jiantao Zhao; Yang Jiao; Jiang-Fei Xu; Xi Zhang

doi:10.1039/C9CC06877E

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Cucurbit[7]uril promoted Fenton oxidation by modulating the redox property of catalysts†

Bohan Tang,‡^a Jiantao Zhao,‡^a Yang Jiao,^a Jiang-Fei Xu

^a and Xi Zhang

*^a

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* Corresponding authors

^a Key Laboratory of Organic Optoelectronics & Molecular Engineering, Department of Chemistry, Tsinghua University, Beijing 100084, China
E-mail: xi@mail.tsinghua.edu.cn

Abstract

The redox property of a ferrocene derivative, the catalyst of Fenton oxidation, is modulated by the host–guest complexation of cucurbit[7]uril. The supramolecularly modulated catalyst significantly accelerates the catalytic oxidation of dye chromophores, thus providing a way to avoid product inhibition and broadening the range of substrates.

This article is part of the themed collection: Cucurbiturils and related cavitands

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Article information

DOI: https://doi.org/10.1039/C9CC06877E
Article type: Communication
Submitted: 04 Sep 2019
Accepted: 29 Oct 2019
First published: 29 Oct 2019

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Chem. Commun., 2019,55, 14127-14130

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Cucurbit[7]uril promoted Fenton oxidation by modulating the redox property of catalysts

B. Tang, J. Zhao, Y. Jiao, J. Xu and X. Zhang, Chem. Commun., 2019, 55, 14127 DOI: 10.1039/C9CC06877E

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Chemical Communications

Cucurbit[7]uril promoted Fenton oxidation by modulating the redox property of catalysts†

Abstract

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Cucurbit[7]uril promoted Fenton oxidation by modulating the redox property of catalysts

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