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Porous organic polymer supported rhodium as a heterogeneous catalyst for hydroformylation of alkynes to α,β-unsaturated aldehydes

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Abstract

A new porous organic polymer supported rhodium catalyst (Rh/POL-BINAPa&PPh3) has been developed for the hydroformylation of various alkynes to afford the corresponding α,β-unsaturated aldehydes with high chem- and stereoselectivity, excellent catalytic activity and good reusability (10 cycles). The heterogeneous catalyst exhibited more catalytic activity than the comparable homogeneous Rh/BINAPa/PPh3 system.

Graphical abstract: Porous organic polymer supported rhodium as a heterogeneous catalyst for hydroformylation of alkynes to α,β-unsaturated aldehydes

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Publication details

The article was received on 03 Sep 2019, accepted on 17 Oct 2019 and first published on 21 Oct 2019


Article type: Communication
DOI: 10.1039/C9CC06834A
Chem. Commun., 2019, Advance Article

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    Porous organic polymer supported rhodium as a heterogeneous catalyst for hydroformylation of alkynes to α,β-unsaturated aldehydes

    Z. Liang, J. Chen, X. Chen, K. Zhang, J. Lv, H. Zhao, G. Zhang, C. Xie, L. Zong and X. Jia, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC06834A

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