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Rhodium catalysed synthesis of seleno-ketals via carbene transfer reactions of diazoesters

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Abstract

Herein, we report on rhodium catalysed carbene transfer reactions of diazoesters with diselenides that result in the formal insertion reaction of the carbene fragment into the Se–Se bond to give seleno-ketals in up to 96% yield (35 examples) via an ionic mechanism.

Graphical abstract: Rhodium catalysed synthesis of seleno-ketals via carbene transfer reactions of diazoesters

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Publication details

The article was received on 02 Sep 2019, accepted on 30 Sep 2019 and first published on 01 Oct 2019


Article type: Communication
DOI: 10.1039/C9CC06830A
Chem. Commun., 2019, Advance Article

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    Rhodium catalysed synthesis of seleno-ketals via carbene transfer reactions of diazoesters

    S. Jana, P. Aseeva and R. M. Koenigs, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC06830A

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