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Asymmetric aerobic oxidation of secondary alcohols catalyzed by poly(N-vinyl-2-pyrrolidone)-stabilized gold clusters modified with cyclodextrin derivatives

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Abstract

Surface modification of poly(N-vinyl-2-pyrrolidone)-stabilized gold clusters (1.8 ± 0.6 nm) with aminated cyclodextrins induced aerobic oxidative kinetic resolution of racemic secondary alcohols (krel = 1.2).

Graphical abstract: Asymmetric aerobic oxidation of secondary alcohols catalyzed by poly(N-vinyl-2-pyrrolidone)-stabilized gold clusters modified with cyclodextrin derivatives

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Publication details

The article was received on 31 Aug 2019, accepted on 30 Oct 2019 and first published on 30 Oct 2019


Article type: Communication
DOI: 10.1039/C9CC06770A
Chem. Commun., 2019, Advance Article

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    Asymmetric aerobic oxidation of secondary alcohols catalyzed by poly(N-vinyl-2-pyrrolidone)-stabilized gold clusters modified with cyclodextrin derivatives

    K. Hirano, S. Takano and T. Tsukuda, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC06770A

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