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The first two examples of halogen bonding with a sigma hole-donating fluorine in the Csp3–F⋯Osp3 interaction from polyfluorinated trans-dihalo-palladium(ii) di-substituted pyridine complexes

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Abstract

The first two examples of halogen bonding in the Csp3–F⋯Osp3 interaction have been both experimentally and theoretically proved for trans-[PdX2(3-HCF2CF2CH2OCH2py)2] complexes where X = Cl and Br. Both metal complexes with a Csp3–F⋯Osp3 halogen bond have a σ hole donating fluorine.

Graphical abstract: The first two examples of halogen bonding with a sigma hole-donating fluorine in the Csp3–F⋯Osp3 interaction from polyfluorinated trans-dihalo-palladium(ii) di-substituted pyridine complexes

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Publication details

The article was received on 29 Aug 2019, accepted on 15 Oct 2019 and first published on 15 Oct 2019


Article type: Communication
DOI: 10.1039/C9CC06731K
Chem. Commun., 2019, Advance Article

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    The first two examples of halogen bonding with a sigma hole-donating fluorine in the Csp3–F⋯Osp3 interaction from polyfluorinated trans-dihalo-palladium(II) di-substituted pyridine complexes

    V. Elakkat, C. Chang, J. Chen, Y. Fang, C. Shen, L. Liu and N. Lu, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC06731K

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