Issue 95, 2019

The first two examples of halogen bonding with a sigma hole-donating fluorine in the Csp3–F⋯Osp3 interaction from polyfluorinated trans-dihalo-palladium(ii) di-substituted pyridine complexes

Abstract

The first two examples of halogen bonding in the Csp3–F⋯Osp3 interaction have been both experimentally and theoretically proved for trans-[PdX2(3-HCF2CF2CH2OCH2py)2] complexes where X = Cl and Br. Both metal complexes with a Csp3–F⋯Osp3 halogen bond have a σ hole donating fluorine.

Graphical abstract: The first two examples of halogen bonding with a sigma hole-donating fluorine in the Csp3–F⋯Osp3 interaction from polyfluorinated trans-dihalo-palladium(ii) di-substituted pyridine complexes

Associated articles

Supplementary files

Article information

Article type
Communication
Submitted
29 Aug 2019
Accepted
15 Oct 2019
First published
15 Oct 2019

Chem. Commun., 2019,55, 14259-14262

The first two examples of halogen bonding with a sigma hole-donating fluorine in the Csp3–F⋯Osp3 interaction from polyfluorinated trans-dihalo-palladium(II) di-substituted pyridine complexes

V. Elakkat, C. Chang, J. Chen, Y. Fang, C. Shen, L. Liu and N. Lu, Chem. Commun., 2019, 55, 14259 DOI: 10.1039/C9CC06731K

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