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Synthesis of a two-dimensional organic–inorganic bismuth iodide metalate through in situ formation of iminium cations

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Abstract

(Me2C[double bond, length as m-dash]NMe2)Bi2I7 represents a new layered organic–inorganic iodido bismuthate. It displays an unprecedented anion topology, a low band gap and good stability. Advanced electronic structure analysis finds the I⋯I interactions to be decisive for the compound's structural and electronic properties.

Graphical abstract: Synthesis of a two-dimensional organic–inorganic bismuth iodide metalate through in situ formation of iminium cations

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The article was received on 26 Aug 2019, accepted on 26 Oct 2019 and first published on 04 Nov 2019


Article type: Communication
DOI: 10.1039/C9CC06625J
Chem. Commun., 2019, Advance Article

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    Synthesis of a two-dimensional organic–inorganic bismuth iodide metalate through in situ formation of iminium cations

    N. Dehnhardt, J. Luy, M. Szabo, M. Wende, R. Tonner and J. Heine, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC06625J

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