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Slow magnetic relaxation in a high-spin pentacoordinate Fe(iii) complex

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Abstract

A mononuclear pentacoordinate iron(III) complex shows slow magnetic relaxation with three relaxation channels. The high-frequency relaxation time of the order of microseconds is prolonged on cooling in accordance with the direct and Raman processes. The low frequency relaxation time is little dependent on temperature and varies in the range τ(LF) = 0.52–0.79 s.

Graphical abstract: Slow magnetic relaxation in a high-spin pentacoordinate Fe(iii) complex

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Publication details

The article was received on 25 Aug 2019, accepted on 23 Oct 2019 and first published on 31 Oct 2019


Article type: Communication
DOI: 10.1039/C9CC06610A
Chem. Commun., 2019, Advance Article

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    Slow magnetic relaxation in a high-spin pentacoordinate Fe(III) complex

    C. Rajnák, J. Titiš, J. Moncoľ, F. Renz and R. Boča, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC06610A

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