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Silver-mediated oxidative 1,2-alkylesterification of styrenes with nitriles and acids via C(sp3)–H functionalization

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Abstract

A new silver-mediated 1,2-alkylesterification of alkenes with nitriles and acids promoted by a catalytic amount of nickel catalyst for producing acyloxylated nitriles has been developed via a C(sp3)–H functionalization process. By employing the NiI2 and Ag2CO3 catalytic systems, the method features broad substrate scope with respect to carboxylic acids, including linear alkyl acids, cyclic acids, aryl acids and amino acids.

Graphical abstract: Silver-mediated oxidative 1,2-alkylesterification of styrenes with nitriles and acids via C(sp3)–H functionalization

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Publication details

The article was received on 20 Aug 2019, accepted on 16 Sep 2019 and first published on 02 Oct 2019


Article type: Communication
DOI: 10.1039/C9CC06437K
Chem. Commun., 2019, Advance Article

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    Silver-mediated oxidative 1,2-alkylesterification of styrenes with nitriles and acids via C(sp3)–H functionalization

    S. Jiang, Y. Wu, S. Luo, F. Teng, R. Song, Y. Xie and J. Li, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC06437K

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