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Molecular spinning top: visualizing the dynamics of M3N@C80 with variable temperature single crystal X-ray diffraction

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Abstract

Variable temperature X-ray diffraction studies on two single crystals containing M3N@C80, i.e., Ho2LuN@C80·NiOEP·2(C6H6) and Lu3N@C80·NiOEP·2(C6H6), (NiOEP = Nickel octaethylporphyrin) unravelled the temperature dependent rotation of the M3N cluster and C80 cage on the static NiOEP molecule.

Graphical abstract: Molecular spinning top: visualizing the dynamics of M3N@C80 with variable temperature single crystal X-ray diffraction

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Publication details

The article was received on 16 Aug 2019, accepted on 07 Oct 2019 and first published on 07 Oct 2019


Article type: Communication
DOI: 10.1039/C9CC06363C
Chem. Commun., 2019, Advance Article

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    Molecular spinning top: visualizing the dynamics of M3N@C80 with variable temperature single crystal X-ray diffraction

    F. Liu and L. Spree, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC06363C

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