Issue 90, 2019
From the journal:

Chemical Communications

Photoinduced charge flow inside an iron porphyrazine complex†

Longteng Tang, ORCID logo a   Liangdong Zhu, ORCID logo a   Maraia E. Ener,b   Hongxin Gao,c   Yanli Wang,a   John T. Groves, ORCID logo c   Thomas G. Spiro ORCID logo *b  and  Chong Fang ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Oregon State University, 153 Gilbert Hall, Corvallis, Oregon 97331, USA
E-mail: Chong.Fang@oregonstate.edu

b Department of Chemistry, University of Washington, Seattle, Washington 98195, USA
E-mail: spirot@uw.edu

c Department of Chemistry, Princeton University, Princeton, New Jersey 08544, USA

Abstract

Tracking inorganic photochemistry with high resolution poses considerable challenges. Here, sub-picosecond electronic and structural motions and MLCT/d–d intersystem crossing in a cationic iron-porphyrazine are probed using ultrafast transient absorption, stimulated Raman spectroscopy, and quantum calculations. By delineating photoinduced energy relaxation, strategies for extending the lifetime of MLCT state are discussed.

Graphical abstract: Photoinduced charge flow inside an iron porphyrazine complex

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Article information

DOI
https://doi.org/10.1039/C9CC06193B
Article type
Communication
Submitted
10 Aug 2019
Accepted
21 Oct 2019
First published
22 Oct 2019

Chem. Commun., 2019,55, 13606-13609

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Photoinduced charge flow inside an iron porphyrazine complex

L. Tang, L. Zhu, M. E. Ener, H. Gao, Y. Wang, J. T. Groves, T. G. Spiro and C. Fang, Chem. Commun., 2019, 55, 13606 DOI: 10.1039/C9CC06193B

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