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Issue 76, 2019
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Unusual rearrangement of modified PNP ligand based Ru complexes relevant to alcohol dehydrogenation catalysis

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Abstract

‘Hangman-type’ PNP pincer ligands and their associated Ru complexes undergo sp2–sp3 C–C bond cleavage and subsequent C–C formation processes to form a new, one carbon unit longer backbone motif. DFT and mechanistic studies suggest a mechanism dependent upon arm pyridine coordination and ligand sterics.

Graphical abstract: Unusual rearrangement of modified PNP ligand based Ru complexes relevant to alcohol dehydrogenation catalysis

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Article information


Submitted
05 Aug 2019
Accepted
21 Aug 2019
First published
21 Aug 2019

Chem. Commun., 2019,55, 11350-11353
Article type
Communication

Unusual rearrangement of modified PNP ligand based Ru complexes relevant to alcohol dehydrogenation catalysis

S. Deolka, N. Tarannam, R. R. Fayzullin, S. Kozuch and E. Khaskin, Chem. Commun., 2019, 55, 11350
DOI: 10.1039/C9CC06024C

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