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Two polyoxovanadate-based metal-organic polyhedra with undiscovered “Near-miss Johnson Solid” geometry†

Abstract

Newfangled frangipani-like [MV5O6(3-O)5(SO4)(COO)5] (M = Nb/W) polyanions serving as 5-connected molecular building blocks (MBBs) that simultaneously assembled with 4-connected [V5O9Cl] MBBs and tricarboxylate ligands (H3BTC) to form two new polyoxovanadate–based metal–organic polyhedra {[MV5O6(3-O)5(SO4)]4[V5O9Cl]4(BTC)12} with undiscovered “Near-miss Johnson Solid” geometry. Moreover, the variable-temperature magnetic susceptibilities were investigated.

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Publication details

The article was received on 01 Aug 2019, accepted on 12 Aug 2019 and first published on 12 Aug 2019


Article type: Communication
DOI: 10.1039/C9CC05984A
Chem. Commun., 2019, Accepted Manuscript

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    Two polyoxovanadate-based metal-organic polyhedra with undiscovered “Near-miss Johnson Solid” geometry†

    Y. Gong, Y. Tao, N. Xu, C. Sun, X. Wang and Z. Su, Chem. Commun., 2019, Accepted Manuscript , DOI: 10.1039/C9CC05984A

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