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[Au7Ag9(dppf)3(CF3CO2)7BF4]n: a linear nanocluster polymer from molecular Au7Ag8 clusters covalently linked by silver atoms

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Abstract

We report the total structure determination of a covalently bonded nanocluster polymer [Au7Ag9(dppf)3(CF3CO2)7BF4]n (1). This features a one-dimensional linear chain, consisting of unique molecular building blocks, Au7Ag8(dppf)3(CF3CO2)7 clusters, which are linked together by Ag–O bonds rather than Au–Au interactions or bidentate organic bridges as previously reported.

Graphical abstract: [Au7Ag9(dppf)3(CF3CO2)7BF4]n: a linear nanocluster polymer from molecular Au7Ag8 clusters covalently linked by silver atoms

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Publication details

The article was received on 30 Jul 2019, accepted on 07 Oct 2019 and first published on 07 Oct 2019


Article type: Communication
DOI: 10.1039/C9CC05924E
Chem. Commun., 2019, Advance Article

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    [Au7Ag9(dppf)3(CF3CO2)7BF4]n: a linear nanocluster polymer from molecular Au7Ag8 clusters covalently linked by silver atoms

    Z. Wen, Z. Guan, Y. Zhang, Y. Lin and Q. Wang, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC05924E

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