[Au7Ag9(dppf)3(CF3CO2)7BF4]n: a linear nanocluster polymer from molecular Au7Ag8 clusters covalently linked by silver atoms

Zhao-Rui Wen; Zong-Jie Guan; Ying Zhang; Yu-Mei Lin; Quan-Ming Wang

doi:10.1039/C9CC05924E

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[Au₇Ag₉(dppf)₃(CF₃CO₂)₇BF₄]_n: a linear nanocluster polymer from molecular Au₇Ag₈ clusters covalently linked by silver atoms†

Zhao-Rui Wen,^a Zong-Jie Guan,^a Ying Zhang,^a Yu-Mei Lin

*^a and Quan-Ming Wang

^ab

Author affiliations

* Corresponding authors

^a Department of Chemistry, College of Chemistry and Chemical Engineering Xiamen, P. R. China

^b Department of Chemistry, Tsinghua University, China
E-mail: linyum@xmu.edu.cn

Abstract

We report the total structure determination of a covalently bonded nanocluster polymer [Au₇Ag₉(dppf)₃(CF₃CO₂)₇BF₄]_n (1). This features a one-dimensional linear chain, consisting of unique molecular building blocks, Au₇Ag₈(dppf)₃(CF₃CO₂)₇ clusters, which are linked together by Ag–O bonds rather than Au–Au interactions or bidentate organic bridges as previously reported.

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Article information

DOI: https://doi.org/10.1039/C9CC05924E
Article type: Communication
Submitted: 30 Jul 2019
Accepted: 07 Oct 2019
First published: 07 Oct 2019

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Chem. Commun., 2019,55, 12992-12995

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[Au₇Ag₉(dppf)₃(CF₃CO₂)₇BF₄]_n: a linear nanocluster polymer from molecular Au₇Ag₈ clusters covalently linked by silver atoms

Z. Wen, Z. Guan, Y. Zhang, Y. Lin and Q. Wang, Chem. Commun., 2019, 55, 12992 DOI: 10.1039/C9CC05924E

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