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Issue 86, 2019
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[Au7Ag9(dppf)3(CF3CO2)7BF4]n: a linear nanocluster polymer from molecular Au7Ag8 clusters covalently linked by silver atoms

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Abstract

We report the total structure determination of a covalently bonded nanocluster polymer [Au7Ag9(dppf)3(CF3CO2)7BF4]n (1). This features a one-dimensional linear chain, consisting of unique molecular building blocks, Au7Ag8(dppf)3(CF3CO2)7 clusters, which are linked together by Ag–O bonds rather than Au–Au interactions or bidentate organic bridges as previously reported.

Graphical abstract: [Au7Ag9(dppf)3(CF3CO2)7BF4]n: a linear nanocluster polymer from molecular Au7Ag8 clusters covalently linked by silver atoms

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Article information


Submitted
30 Jul 2019
Accepted
07 Oct 2019
First published
07 Oct 2019

Chem. Commun., 2019,55, 12992-12995
Article type
Communication

[Au7Ag9(dppf)3(CF3CO2)7BF4]n: a linear nanocluster polymer from molecular Au7Ag8 clusters covalently linked by silver atoms

Z. Wen, Z. Guan, Y. Zhang, Y. Lin and Q. Wang, Chem. Commun., 2019, 55, 12992
DOI: 10.1039/C9CC05924E

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