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Issue 78, 2019
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Inorganic–organic hybrid high-dimensional polyoxotantalates and their structural transformations triggered by water

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Abstract

The first two inorganic–organic hybrid three-dimensional (3D) polyoxotantalates (POTas) and the first two inorganic–organic hybrid 2D POTas have been obtained. All of these high-dimensional POTas are built from a new-type POTa dimeric cluster {Cu(en)(Ta6O19)}2/{Cu(enMe)(Ta6O19)}2 (en = ethylenediamine, enMe = 1,2-diaminopropane) bridged by copper complexes. Interestingly, extended POTas 1 and 3 can undergo single-crystal to single-crystal structural transformations triggered by water.

Graphical abstract: Inorganic–organic hybrid high-dimensional polyoxotantalates and their structural transformations triggered by water

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Article information


Submitted
29 Jul 2019
Accepted
30 Aug 2019
First published
30 Aug 2019

Chem. Commun., 2019,55, 11735-11738
Article type
Communication

Inorganic–organic hybrid high-dimensional polyoxotantalates and their structural transformations triggered by water

Z. Li, J. Zhang, L. Lin, J. Liu, X. Li and S. Zheng, Chem. Commun., 2019, 55, 11735
DOI: 10.1039/C9CC05884B

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