Issue 78, 2019

Inorganic–organic hybrid high-dimensional polyoxotantalates and their structural transformations triggered by water

Abstract

The first two inorganic–organic hybrid three-dimensional (3D) polyoxotantalates (POTas) and the first two inorganic–organic hybrid 2D POTas have been obtained. All of these high-dimensional POTas are built from a new-type POTa dimeric cluster {Cu(en)(Ta6O19)}2/{Cu(enMe)(Ta6O19)}2 (en = ethylenediamine, enMe = 1,2-diaminopropane) bridged by copper complexes. Interestingly, extended POTas 1 and 3 can undergo single-crystal to single-crystal structural transformations triggered by water.

Graphical abstract: Inorganic–organic hybrid high-dimensional polyoxotantalates and their structural transformations triggered by water

Supplementary files

Article information

Article type
Communication
Submitted
29 Jul 2019
Accepted
30 Aug 2019
First published
30 Aug 2019

Chem. Commun., 2019,55, 11735-11738

Inorganic–organic hybrid high-dimensional polyoxotantalates and their structural transformations triggered by water

Z. Li, J. Zhang, L. Lin, J. Liu, X. Li and S. Zheng, Chem. Commun., 2019, 55, 11735 DOI: 10.1039/C9CC05884B

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