Issue 83, 2019

Zn(OAc)2-catalyzed tandem cyclization of isocyanides, α-diazoketones, and anhydrides: a general route to polysubstituted maleimides

Abstract

A novel Zn(OAc)2-catalyzed three-component tandem cyclization reaction of isocyanides, α-diazoketones and anhydrides has been developed. The reaction demonstrates the wide scope of substrates and provides a novel and efficient strategy for the synthesis of polysubstituted maleimides from readily available substrates in a single step.

Graphical abstract: Zn(OAc)2-catalyzed tandem cyclization of isocyanides, α-diazoketones, and anhydrides: a general route to polysubstituted maleimides

Supplementary files

Article information

Article type
Communication
Submitted
26 Jul 2019
Accepted
25 Sep 2019
First published
26 Sep 2019

Chem. Commun., 2019,55, 12519-12522

Zn(OAc)2-catalyzed tandem cyclization of isocyanides, α-diazoketones, and anhydrides: a general route to polysubstituted maleimides

Y. Liang, X. Meng, M. Yang, H. Mehfooz and Y. Zhao, Chem. Commun., 2019, 55, 12519 DOI: 10.1039/C9CC05802H

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