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Wide-pH-range stable crystalline framework based on the largest tin-oxysulfide cluster [Sn20O10S34]

Abstract

We report herein a diamond-like oxysulfide framework, 3D-T4-SnOS, based on the largest supertetrahedral cluster of Sn4+ ions, viz. “[Sn20O10S34]”, that remains intact in aqueous solution with pH-range between 1∼14, and has narrower optical bandgap, red-shifted fluorescence emission, and enhanced photoelectric response compared to the smaller version, 2D-T3-SnOS, with building unit of the supertetrahedral “[Sn10O4S20]”.

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Publication details

The article was received on 24 Jul 2019, accepted on 12 Aug 2019 and first published on 13 Aug 2019


Article type: Communication
DOI: 10.1039/C9CC05736F
Chem. Commun., 2019, Accepted Manuscript

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    Wide-pH-range stable crystalline framework based on the largest tin-oxysulfide cluster [Sn20O10S34]

    S. Huang, L. He, E. Chen, H. Lai, J. Zhang and Q. Lin, Chem. Commun., 2019, Accepted Manuscript , DOI: 10.1039/C9CC05736F

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