Issue 79, 2019
From the journal:

Chemical Communications

Tetrahedral iron featuring an appended Lewis acid: distinct pathways for the reduction of hydroxylamine and hydrazine†

John J. Kiernicki,a   Emily E. Norwine,a   Matthias Zellerb  and  Nathaniel K. Szymczak ORCID logo *a  

* Corresponding authors

a University of Michigan, 930 N. University, Ann Arbor, MI 48109, USA
E-mail: nszym@umich.edu

b H. C. Brown Laboratory, Purdue University, 560 Oval Dr, West Lafayette, IN 47907, USA

Abstract

We present the preparation of a nitrogen-based bidentate ligand featuring an appended boron Lewis acid as well as its tetrahedral Fe2+ and Zn2+ complexes. These complexes act as platforms for hydrazine and hydroxylamine capture and reduction chemistry.

Graphical abstract: Tetrahedral iron featuring an appended Lewis acid: distinct pathways for the reduction of hydroxylamine and hydrazine

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Article information

DOI
https://doi.org/10.1039/C9CC05720J
Article type
Communication
Submitted
23 Jul 2019
Accepted
29 Aug 2019
First published
17 Sep 2019

Chem. Commun., 2019,55, 11896-11899

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Tetrahedral iron featuring an appended Lewis acid: distinct pathways for the reduction of hydroxylamine and hydrazine

J. J. Kiernicki, E. E. Norwine, M. Zeller and N. K. Szymczak, Chem. Commun., 2019, 55, 11896 DOI: 10.1039/C9CC05720J

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