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Gold(i)-catalyzed pathway-switchable tandem cycloisomerizations to indolizino[8,7-b]indole and indolo[2,3-a]quinolizine derivatives

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Abstract

Experimental and theoretical explorations were performed on the pathways of the cascade cycloisomerizations of tryptamine-N-ethynylpropiolamide substrates. The methodology provided a common strategy to access either indolizino[8,7-b]indoles or indolo[2,3-a]quinolizines in a switchable fashion.

Graphical abstract: Gold(i)-catalyzed pathway-switchable tandem cycloisomerizations to indolizino[8,7-b]indole and indolo[2,3-a]quinolizine derivatives

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Publication details

The article was received on 23 Jul 2019, accepted on 18 Oct 2019 and first published on 18 Oct 2019


Article type: Communication
DOI: 10.1039/C9CC05667J
Chem. Commun., 2019, Advance Article

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    Gold(I)-catalyzed pathway-switchable tandem cycloisomerizations to indolizino[8,7-b]indole and indolo[2,3-a]quinolizine derivatives

    C. Liu, Z. Sun, F. Xie, G. Liang, L. Yang, Y. Li, M. Cheng, B. Lin and Y. Liu, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC05667J

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