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Low valent lead hydride chemistry: hydroplumbylation of phenylacetylene and 1,1-dimethylallene

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Abstract

Hydroplumbylation reactions of the low valent organolead hydride [(Ar*PbH)2] with phenylacetylene and 1,1-dimethylallene are presented. A vinyl plumbylene was isolated in the case of the alkyne reaction exhibiting a down field NMR signal for the CH unit attached to the low valent heavy atom. 1,1-Dimethylallene affords formation of an allyl plumbylene.

Graphical abstract: Low valent lead hydride chemistry: hydroplumbylation of phenylacetylene and 1,1-dimethylallene

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Publication details

The article was received on 15 Jul 2019, accepted on 31 Jul 2019 and first published on 01 Aug 2019


Article type: Communication
DOI: 10.1039/C9CC05431F
Chem. Commun., 2019, Advance Article

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    Low valent lead hydride chemistry: hydroplumbylation of phenylacetylene and 1,1-dimethylallene

    S. Weiß, H. Schubert and L. Wesemann, Chem. Commun., 2019, Advance Article , DOI: 10.1039/C9CC05431F

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