SCHEDULED MAINTENANCE
Hydroplumbylation reactions of the low valent organolead hydride [(Ar*PbH)2] with phenylacetylene and 1,1-dimethylallene are presented. A vinyl plumbylene was isolated in the case of the alkyne reaction exhibiting a down field NMR signal for the CH unit attached to the low valent heavy atom. 1,1-Dimethylallene affords formation of an allyl plumbylene.
S. Weiß, H. Schubert and L. Wesemann, Chem. Commun., 2019, 55, 10238 DOI: 10.1039/C9CC05431F
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